Data Quality Objectives for Remedy Selection – A Working Session

 

THIS SESSION IS NOT CONCURRENT WITH THE OTHERS

Remedial investigations often leave data gaps that make evaluation and selection of remediation alternatives difficult.  This special working session will: identify the data requirements to evaluate and scope some common and innovative technologies; describe methods for streamlining the RI/FS process to accelerate remedy selection; explore barriers to collection of necessary data.  Investigation, remedial evaluation, and technology experts will present technology overviews, data requirements, and case studies.  A robust roundtable discussion involving the panel and the audience will follow.

Introduction and Moderator
Chris Mitchell, AECOM, Westfield, MA 

State of the Practice for Site Investigation
Ernest Ashley, CDM, Cambridge, MA

Performing Feasibility Evaluations with Incomplete Conceptual Site Models
Daniel Groher, PE, AECOM, Westfield, MA

Scoping In-Situ Bioremediation
Maureen Dooley, Regenesis, Inc., Wakefield, MA

Pricing an Excavation Based Remedy – A Working Session
Jon Simpson, Charter Environmental

Issues of Scoping Chemical Oxidation-Based Remediation
George E Hoag, VeruTEK Technologies, Inc., Bloomfield, CT
John Collins,
VeruTEK Technologies, Inc., Bloomfield, CT

Source Zone Delineation Techniques and Needs for Thermal Remediation 
John LaChance, TerraTherm, Inc., Fitchburg, MA 
Gorm Heron, TerraTherm, Inc., Keene, CA 
Ralph S. Baker, TerraTherm, Inc., Fitchburg, MA

Panel Discussion:  Roundtable Working Session to Evaluate Data Quality Objectives
Ernest Ashley, CDM, Cambridge, MA
Maureen Dooley, Regenesis, Inc., Wakefield, MA
Daniel
Groher, PE, AECOM, Westfield, MA
George E Hoag, VeruTEK Technologies, Inc
John LaChance, TerraTherm, Inc., Fitchburg, MA
Chris Mitchell, AECOM,
Westfield, MA
John Simpson, Charter Environmental

 

State of the Practice for Site Investigation 

Ernest C. Ashley, P.G., LSP, LEP, CHMM, Camp Dresser & McKee Inc., One Cambridge Place, 50 Hampshire Street, Cambridge, MA 02139, Tel: 617-452-6416, Email: ashleyec@cdm.com 

Remedial investigations often leave data gaps that make evaluation and selection of remediation alternatives difficult.  Many factors including budget, schedule, unfocused approaches, inadequate or inappropriate data collection all contribute to limit the scope of remedial investigations resulting in incomplete conceptual site models and insufficient data to make sound remedial decisions and prepare remedial designs.  This portion of this special working session will identify the data requirements to evaluate and scope some common and innovative technologies; explore barriers to collection of necessary data; and describe methods for streamlining the RI/FS process to accelerate remedy selection.

Performing Feasibility Evaluations with Incomplete Conceptual Site Models
Daniel Groher, PE, AECOM, 2 Technology Park Drive, Westford, MA, 01886, Tel: 978-589-3000, Email: daniel.groher@aecom.com

Remediation engineers are often asked to develop strategies, cost estimates, and even make detailed proposals for soil and groundwater remediation with sparse site data.  Even sites that have been extensively investigated can have crucial data gaps that make remediation selection and costing uncertain.  Typical remedial site investigations are designed to understand the nature and extent of the “contamination” at the site with a focus on evaluating potential risks to human health and the environment.  While these are appropriate and necessary objectives for a remedial investigation, they often result in site databases that are insufficient for accurately evaluating remediation alternatives.  Different site remediation approaches require technology-specific site data, such as contaminant mass, stratigraphic details, or bio-geochemical aquifer conditions.  For example, assessment of the suitability and cost of in-situ chemical oxidation depends on knowledge of total oxidant demand in an aquifer.  At sites many sites, the contaminants of concern that are the focus of the RI are only a small fraction of the total organic carbon (TOC) in the subsurface, which may drive the feasibility of ISCO for that site.   Knowledge of TOC is often a key element of the conceptual site model (CSM) that is required to fully evaluate remediation technologies.

Performing feasibility evaluations with incomplete CSMs is as much art as science.  When key site data cannot be collected due to financial or schedule limitations, the necessary parameters must be inferred from other site data, experience, and good engineering judgment.  This presentation will discuss some of the common data gaps that are encountered when performing remediation feasibility evaluations and some techniques for performing FS evaluations with sparse data.

Scoping In-Situ Bioremediation

Maureen Dooley, Regenesis, 19 Belmont Road, Wakefield, MA, Tel: 781 245-1320, Fax: 781 245-1329, Email: mdooley@regenesis.com

Bioremediation is a microbially mediated approach that can be used to treat a wide range of contaminants such as petroleum hydrocarbons and chlorinated solvents within a diverse range of hydrogeological settings.  Successful enhanced, in-situ bioremediation projects are often a function of supplying enough injectable electron donor or electron acceptor material to meet contaminant and geochemical “demand” as well as the ability to effectively distribute these materials.  Another important consideration for enhanced bioremediation projects is the selection and or use of injectables that can maintain optimal subsurface conditions long enough so that treatment objectives can be met.  The presentation/discussion will include recommendations for data collection, setting realistic expectations, trouble shooting suggestions and lessons learned from our experience with design and review of thousands of enhanced bioremediation projects using controlled-release injectables. 

Pricing an Excavation Based Remedy – A Working Session

Jon Simpson, Project Manager, Charter Environmental, Inc., 72 Jonspin Road, Wilmington, MA 01887, Tel: 978-658-2232 x201, Fax: 978-658-4505

Understanding the chemical, physical, and capacity limitations of today’s offsite recycling and disposal options are one of most important aspects of keeping a large scale soil removal project on time and on budget. Missing the opportunity to gather key soils information during the development of a pre-characterization program can drive bid prices up as contractors attempt to cover potential cost exposures or result in large change-orders once the project is underway.

Issues of Scoping Chemical Oxidation-Based Remediation

George E. Hoag, Ph.D., VeruTEK Technologies, Inc., 65 West Dudley Town Road, Suite 100, Bloomfield, CT 06002, Office: 860-242-9800 ext. 301, Fax: 860-242-9899, Email:ghoag@verutek.com
John Collins, Ph.D.,
VeruTEK Technologies, Inc., 65 West Dudley Town Road, Suite 100, Bloomfield, CT 06002, USA, Tel: 860-242-9800 ext. 300, Fax: 860-242-9899, Email:jcollins@verutek.com

The conversation…

ABC123 Consulting: Can you provide me with a full-scale cost estimate for using In-Situ Chemical Oxidation (ISCO) and your new Surfactant Enhanced Chemical Oxidation (S-ISCOTM) Technology?

Hoag: What is the estimate for?

ABC123 Consulting: We need to finalize a Feasibility Study (FS) by Friday [it’s Wednesday]. I can email the information that we have on this site, we want to clean-up the groundwater, it’s only a groundwater problem.

Hoag: How big is the site, what’s the hydrogeology like, do you have soil data, are there any Non Aqueous Phase Liquids, what are the receptors?

ABC123 Consulting: The groundwater plume covers about 3 acres and the saturated thickness is about 15 feet and goes to bedrock, but we don’t have any bedrock wells.  We only have a few soil analyses, because it’s a groundwater problem, we need to meet the State’s unrestricted use standards. We haven’t seen any NAPLs at the site but we have tetrachloroethylene (PCE) concentrations at 50 ppm, so there is a possibility there could be some sorbed phase materials.  We have delineated to non-detect in the overburden groundwater. There are no receptors, we just need to meet groundwater standards.

Hoag: What is the source of the PCE?

ABC123 Consulting:  This was a compressor refurbishing facility and there was a drum storage area that was removed and we excavated 1000 cubic yards of material and the source area was removed.

Hoag:  Did you ever test soils or groundwater for Total Petroleum Hydrocarbons.  Do you know the oxidation-reduction potential (ORP) of the groundwater?  Have you estimated the mass of contaminants in the subsurface?

ABC123 Consulting:  No, we ran semivolatiles and there were none and we haven’t done any TPH as a result.  The groundwater is reducing in the zone immediately downgradient of the former source area, but is oxidizing over most of the plume.  We have made a mass estimate based on groundwater concentrations and the measured foc of the soil.

This presentation will identify what is wrong with this all too common scenario. Realistic data needs are discussed necessary to conduct chemical oxidation and surfactant enhanced chemical oxidation in the subsurface.  The focus of this presentation will be an analysis of the disconnect between RI/FS-modeled data collection, interpretation, technology screening, decision making and remedy implementation needs.  Recommendations are made to streamline the RI/FS process with input from remediation technology specialists. 

Source Zone Delineation Techniques and Needs for Thermal Remediation 

John LaChance, TerraTherm, Inc., 10 Stevens Road, Fitchburg, MA 01420, Tel: 978-343-0300, Fax: 978-343-2727, Email: Jlachance@terratherm.com
Gorm Heron, TerraTherm, Inc., 28900 Indian Point, Keene, CA  93531, Tel and Fax: 661-823-1620, Email: Gheron@terratherm.com
Ralph S. Baker,
TerraTherm, Inc., 10 Stevens Road, Fitchburg, MA 01420, Tel: 978-343-0300, Fax: 978-343-2727, Email: Rbaker@terratherm.com

When applied correctly, in situ thermal remediation is a robust and efficient approach for cleaning up source zones contaminated with organic chemicals.  For example, thermal remediation has been successfully used to achieve stringent cleanup goals (e.g., residential standards) even at sites contaminated with chlorinated volatile organic compounds (VOCs) occurring as dense non-aqueous phase liquids (NAPL), and high-boiling point chemicals such as polycyclic aromatic hydrocarbons.  However, the successful application of thermal remediation first requires development of an accurate conceptual model of the source zone and the surrounding site that includes the following:

  • Nature and extent of contamination; including: VOCs, semi-volatile organic compounds, and the presence of NAPL;
  • Estimate of contaminant mass present in the treatment zone;
  • Soil stratigraphy (soil type, grain size distribution, permeability);
  • Bedrock lithology and nature and occurrence of fractures (if applicable);
  • Groundwater flux rates through soil and bedrock; and
  • Remedial goals (soil and/or groundwater concentrations, percent reductions).

This presentation discusses how these data are used to (a) select the proper thermal remediation approach and technology and (b) design an effective and efficient thermal remediation system.  With this understanding, we will then work backwards to present the types of information and level of detail required for the conceptual model.  Effective methods and strategies to obtain this information from the field will also be covered. 

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