Conference Program
INNOVATIVE TECHNOLOGIES Poster Session

Innovative Methods of Treating Groundwater and Soil Gas Containing VOCs and SVOCs

Shannon L. Daigle and Craig C. Lizotte, Environmental Science Services, Inc. and Kelly J. McQueeney, Envirogen, Inc.

A 93-acre site containing a variety of Volatile Organic Compounds (VOCs) and Semi-Volatile Organic Compounds (SVOCs) in soil and groundwater will be remediated by hydraulically containing groundwater at the site perimeter, dewatering the source area then applying Soil Vapor Extraction (SVE) to the dewatered vadose zone soil. Site hydraulic control is achieved by pumping groundwater from four perimeter wells installed to depths of approximately 60 feet. Dewatering in the 9-acre source area is achieved through groundwater pumping at 37 dual extraction wells installed to depths between approximately 40 and 60 feet. Inorganics in the extracted groundwater are removed by single stage pH precipitation/flocculation, clarification and filtration. SVOCs and VOCs are destroyed by a 60 kW Ultraviolet Oxidation system, a 900 scfm shallow tray air stripper, two 2,000 pound peroxide destruction units, and two 2,000 pound carbon polish units. The SVE treatment system consists of 46 shallow and 86 deep SVE wells, operating at wellhead vacuums of 8 to 16 inches of mercury vacuum. The design air extraction rate of the SVE system is approximately 2,200 scfm. Soil gas is drawn from the vadose zone using a combination of two 100-Hp and one 25-Hp rotary positive displacement blowers. Extracted soil gas is treated through a 1.0 MMBTU/hr Catalytic Oxidation unit using propane as a supplemental fuel. Acid gases, generated by the oxidation of chlorinated solvents, are then removed from the treated vapor stream using an acid gas scrubber. Treated soil gas effluent is combined with, treated groundwater treatment system offgas and discharged to the atmosphere through a 65 foot steel, fiberglass reinforced polyethylene lined discharge stack. To date, preliminary testing indicates the groundwater treatment system has achieved over 99.9% destruction of VOCs and SVOCs. The vapor treatment system has yet to be activated.

Commercializing Innovative Technologies in the Environmental Remediation Marketplace

David L. Fleming, Thermal Remediation Services, Inc.

As new, innovative technologies transition from the laboratory to the commercial marketplace they are often caught in the "Valley of Death" so to speak where the commercializing process can stagnate and end. The "Valley of Death" refers to a point in time during commercialization where the technology provider or vendor exhausts their resources, gets stuck and goes out of business.

This presentation will focus on how to avoid the "Valley of Death" and the steps to take to climb the mountain of successful technology deployment. A commercializing model will be presented that incorporates team building and leveraging existing networks and resources that were utilized for the deployment of the Six-Phase Heating (SPH) technology.

An Innovative Technology for Characterizing Hydrocarbon Contaminated Sites

Dr. Pradeep U. Kurup, Ceretha M. Fernandes, and Deepti K. Nair, University of Massachusetts Lowell

Substantial amounts of resources are being spent every year for subsurface investigations to characterize and clean-up contaminated sites. Conventional methods of site characterization based on borehole drilling, sampling and laboratory testing is time consuming, expensive, and require disposal of contaminated drilling fluids, cuttings and soil samples. There is also the added risk of human exposure to toxic chemicals. Volatile organic compounds (VOCs) such as Benzene, Toluene, Ethylbenzene, Xylene, and TCE are found in a variety of products like gasoline, paints, plastics, and solvents. These VOCs are important environmental contaminants because they are mobile, persistent and toxic. This paper describes a novel in-situ technology for characterizing VOCs in soils, sediments and water by automated odor recognition. A prototype "Electronic Nose" has been developed for rapidly sniffing and characterizing vapors. The two main components of the electronic nose are the sensing system that mimics the biological nose, and the automated pattern recognition system that simulates the human brain. The pattern recognition system is based on computational paradigms such as artificial neural networks and principal component analysis. The sensing system is an array of several different chemical sensors. Each chemical vapor presented to the sensor array produces a signature or pattern characteristic of the vapor. Different chemicals are presented to the sensor array, to build a database of signatures. This database of labeled signatures is then used to train a pattern recognition system. The trained neural network model is capable of uniquely identifying vapors by making comparisons with the library of signatures in its database. Future research will involve integrating this novel sensing technology with an in situ probe for safe, rapid, and economical characterization of contaminated sites.

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