Modeling
Zinc and Sodium Chloride Migration in Vadose Zone Soils
Beneath Stormwater
Infiltration Devices
J.
Bradley Mikula, Penn State Harrisburg, 777 West Harrisburg
Pike, TL 105, Middletown, PA, 17057, Tel: 717-948-6358,
Fax: 717-948-6580, Email: jum170@psu.edu
Shirley E. Clark, Penn State Harrisburg, 777 West
Harrisburg Pike, TL 173, Middletown, PA, 17057, Tel:
717-948-6127, Fax: 717-948-6580, Email: sec16@psu.edu
Katherine H. Baker, Penn State Harrisburg, 777 West
Harrisburg Pike, TL 105, Middletown, PA, 17057, Tel:
717-948-6308, Fax: 717-948-6580, Email: khb4@psu.edu
Urbanization
has been responsible for an increase in the amount of
impervious surfaces, leading to an increase in stormwater
runoff and a decrease in groundwater recharge. Stormwater
runoff contains pollutants, such as nutrients, pathogens,
heavy metals, solids, organic compounds, pesticides, and
chlorides, which have greatly contributed to the
degradation of receiving waters due to surface discharge
of stormwater. A high demand for groundwater combined with
a decrease in stormwater infiltration locations also has
led to a decline in water tables. This has prompted
stormwater managers to consider implementing more
infiltration practices into their designs. However, past
studies have shown that infiltrating stormwater could
contaminate the groundwater, and in some cases
contamination actually has occurred. Therefore, methods
for easily predicting contamination potential need to be
developed.
Stormwater
pollutants interact with the soils in the unsaturated zone
as they migrate towards the groundwater. The specific type
of soil and its properties have a profound effect on the
movement of water and pollutants. Through the use of the
SESOIL model, this research will evaluate which soils are
best for preventing stormwater pollutants from reaching
the groundwater, while still allowing groundwater
recharge. Factors such as pollutant concentration,
rainfall, depth to groundwater, hydraulic conductivity,
organic content, and soil pH will be evaluated to
determine which ones have the greatest influence on
pollutant migration. They will be evaluated using a
factorial design analysis. Zinc and sodium chloride were
chosen to be the pollutants of interest because of their
prevalence in stormwater, solubility, and differing
migration rates. Initial concentrations used in the model
ranged between 32 and 2100 μg/L of zinc and 69 and
3400 mg/L of sodium chloride. In addition, long-term
simulations using actual rainfall data will be performed
to evaluate the effects of frequent storms and drought
conditions on predicted pollutant movement.
Testing
New Capabilities for Simulating Free and Dissolved Phase
Transport using MT3DMS
Matthew
Tonkin, S.S. Papadopulos & Associates, Inc, 120
Main Street, Rt. 6A, Yarmouth Port, MA, 02675, Tel:
508-362-7014, Email: matt@sspa.com
Chunmiao Zheng, Professor of Hydrogeology and SSPA Faculty
Fellow, Department of Geological Sciences, University of
Alabama, Tuscaloosa, AL, 35487, Tel: 205-348-0579, Email:
czheng@ua.edu
Jim Weaver, US EPA, Office of Research and Development,
Athens, GA, Tel: (706) 355-8329; Email: weaver.jim@epa.gov
Chris
Muffels, S.S. Papadopulos & Associates, Inc, 7944
Wisconsin Avenue, Bethesda, MD, 20814, Tel: 301-718-8900,
Email: cmuffels@sspa.com
The
vadose zone free-phase simulation capabilities of the US
EPA Hydrocarbon Spill Screening Model (HSSM) were recently
linked with the multi-species dissolved-phase contaminant
transport simulator MT3DMS.
The HSSM simulates a spill release, its
one-dimensional migration to the water table, and the
development and dissolution of a floating lens of product
upon the water table. The linkage enables the analytical
treatment of vadose zone transport from multiple
spill-type sources to be included in a numerical
simulation of dissolved-phase aquifer contamination. The
codes were linked by compiling relevant modules of the
HSSM as a Dynamic Link Library (DLL), and developing a
time-varying source package for MT3DMS referred to as the
Hydrocarbon Spill Source Interface Package (HSS Package).
We outline the approach adopted for linking the simulation
codes, and present a real-world groundwater
flow-and-transport simulation in which MT3DMS executes the
HSS Package. This simulation illustrates some benefits of the linked
simulation approach, in particular the simultaneous
calibration of parameters from both models to field data
using programs developed to support the use of the HSS
Package with PEST.
EPA
Disclaimer
Although this work was reviewed by EPA and approved for
publication, it may not necessarily reflect official
Agency policy. Mention of trade names or commercial
products does not constitute endorsement or
recommendation for use.
Top
|